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PHYSICAL PROPERTIES can
be determined without changing the chemical composition of the compound.
By determining physical properties, chemists are able to classify
compounds. Some physical properties include:
- Color
- State of matter
- is it a solid, liquid or gas?
- Melting point - the temperature
range at which the substance melts, when it changes from
a solid state to a liquid state. The melting point of a substance
can be measured using several techniques. The most common apparatus
used is called a Mel-Temp. You can watch a video demonstrating
the determination of melting point using a Mel-Temp on the videos
webpage.
- Boiling point - the temperature
at which the substance boils, when it changes from a liquid state
to a gaseous state.
- Solubility - the amount of
a compound which can dissolved in a given mass of a solvent such
as water. The phrase "like dissolves like" indicates
that a knowledge of which solvents are effective in dissolving
an unknown compound is helpful in characterizing the unknown compound.
Polar solvents dissolve other polar molecular compound and ionic
compounds. Nonpolar solvents will dissolve other nonpolar molecular
compounds. You can watch a video demonstrating the determination
of solubility on the videos
webpage.
Terms:
- When referring to a compound in its solid state, the
compound is either soluble or insoluble in a solvent.
- When referring to a compound in its liquid state, the
compound is either miscible or immiscible in a
solvent.
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soluble
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insoluble
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miscible
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immiscible
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- Density
- the volume which is occupied by a specific mass of a
material, usually given in units of grams per cubic centimeters
or grams per milliliter. The density of a liquid can be determined
by weighing a exact volume and calculating density using the equation
below.
The volume of a solid can be difficult to measure, so its density
is determined using a different method. The volume is found
by measuring the volume of a liquid that the solid displaces.
In the example below, the volume of the compound is 17.2 mL
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Volume of water= 15.0 mL
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Volume of water + compound = 32.2 mL
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- Electrical conductivity -
the ability of a material to conduct an electric current.
Solids: Of the solid materials, only metals conduct
an electric current.
Pure Liquids:
- Metals in the molten state conduct an electric current
- Molten ionic compounds (salts) conduct an electric current
because of ion migration.
- Molten or liquid molecular compounds do not conduct an electric
current since no ions are present, only molecules.
Water Solutions of Compounds: Compounds that dissolve
in water to yield solutions that conduct electricity are called
electrolytes. Conductivity in water solution is due to the presence
of ions. Materials that dissociate 100% into ions are called
strong electrolytes. Those that dissociate into ions to a small
extent are called weak electrolytes. Compounds that dissolve
in water but do not dissociate into ions and whose solutions
do not conduct electricity are called non-electrolytes.
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